The GOG library has been building since 2008, when Vista was the current windows version.
Some titles that worked at some point over the last 16 years may have some developed issues on modern hardware, drivers, or operating systems.
This program is at least confirming it works on windows 10/11 and common 2024 hardware
It had different names depending on publisher/region:
Little Big Adventure […] was published in Europe by Electronic Arts, and by Activision in North America, Asia and Oceania under the name Relentless: Twinsen’s Adventure.
https://en.wikipedia.org/wiki/Little_Big_Adventure